A homoleptic phosphine adduct of Tl(I).
نویسندگان
چکیده
A homoleptic phosphine adduct of thallium(I) supported by a tris(phosphino)borate ligand has been isolated and structurally characterized.
منابع مشابه
Electrophilic activation and the formation of an unusual Tl+/Cr3+ tetranuclear ion-complex adduct.
Reaction of TlPF(6) with the Cr(III) complex fac-[CrCl(3)(NPN)] (NPN = bis(2-picolyl)phenyl phosphine) did not lead to precipitation of TlCl but rather to addition of the Tl(+) cation to the CrCl(3) moiety, which resulted in a pseudo-dimeric adduct which has an unusual tetranuclear centrosymmetric structure in the solid state.
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عنوان ژورنال:
- Chemical communications
دوره 20 شماره
صفحات -
تاریخ انتشار 2001